How to get unblocked from Live, Hotmail and Outlook
If your e-mail account or hosting has been compromised by a spam bot, you may find yourself blocked from sending e-mails to Microsoft e-mail addresses including any @live.com, @hotmail.com and @outlook.com accounts.
Once you have established and rectified the cause, you can contact Microsoft directly with your e-mail address and server details so that you can be removed from their block list by visiting https://support.microsoft.com/en-us/getsupport?oaspworkflow=start_1.0.0.0&wfname=capsub&productkey=edfsmsbl3&ccsid=635688189955348624&wa=wsignin1.0